If you have 3GS iPhone and haven't upgraded to iOS 4.3 you won't receive the Three's settings via iTunes, until you upgrade your iPhone to iOS 4.3. If you decide not to upgrade to iOS 4.3 you can enter the settings manually by following these steps:
Planet 3 and My3
Planet 3 gives you quick access to My3 where you can top-up your phone, buy Add-ons, check how many minutes and texts you have left and also pay your bill.
You must be connected to the Three network to use Planet 3 and My3. The best way to make sure you are connected to Three is to turn off Wi-Fi.
To access Planet 3 just tap on Safari on the home screen and enter:

Please note if you have upgraded to iSO 4.3 you cannot enter settings manually. You can find out more about settings here.